DEVELOPMENT OF A MODIFIER FOR GIVING MATERIALS FROM EFFICIENTLY PROCESSED WOOD BIOMASS SPECIAL PROPERTIES
Abstract
Background. Wood is a unique material in its structure. However, materials made from wood raw materials have such negative properties as insufficient bio- and fire-resistance. In turn, when organizing and improving the efficiency of logging activity, large amounts of practically unused cutting residues is produced. Their modification for the purposes of the forest industry is an effective tool for creating many valuable and demanded products. In particular, arilazo-β-dicarbonyl compounds are widely used as syntons for the production of heterocyclic compounds. Among heterocycles, a large number of compounds have found application in the form of biologically active substances that have been successfully and for a long time used as pesticides for the wood processing industry.
Purpose. Synthesis of p-nitrophenyl hydrobutanons, cyclocondensation to form pyrazoles and study of their chemical properties of the substances first obtained. Proof of structure by modern spectral analysis methods.
Materials and Methods. Research methods include: organic synthesis; UV spectrometry, 1H NMR, 13H NMR.
Results. Four new compounds were synthesized: 4-methoxy-1-(p-chloro(bromo)phenyl)-2-(p-nitrophenylhydrazo)-1,2,3-butantrions and 3(5)-methoxy-5(3)-(p-chloro(bromo)phenyl)-4-(p-nitrophenylhydrazo)-1H-pyrazoles. Amines were prepared by the reduction of the related nitrosopyrazoles. The acylation reaction was demonstrated for the obtained amine. The structures of all synthesized compounds were proved by modern methods of analysis.
Conclusion. Thus, we synthesized p-nitrophenylhydrazobutanetriones with a chloro(bromo)phenyl substituent, their cyclization products with hydrazine, and N-(5-(4-chloro(bromo)phenyl)-3-(methoxymethyl)-1H-pyrazole-4-yl)acetamides based on them. The structure of the obtained substances was determined by spectral methods of analysis.
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